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Transactions of the INDIAN CERAMIC SOCIETY   Vol. 63  2004
Kinetics of Non-Isothermal and Isothermal Decomposition of Limestone
H. S. Tripathi, A. Ghosh and B. Mukherjee
Pages : 155-158
DOI :10.1080/0371750X.2004.11012154
Abstract
The kinetics of decomposition of limestone was studied using both non-isothermal and isothermal methods. The mechanism and kinetics of thermal decomposition were studied using Arrhenius equation applied to solid state reactions. It was found that in both non-isothermal and isothermal methods limestone seemed to be decomposed via a zero order reaction mechanism. The energy of activation for the non-isothermal and isothermal decompositions of limestone was 157.79 and 181.43 kJ.mol–1 respectively. Similarly, lnA values for non-isothermal and isothermal decomposition were found to be 14.2 and 13.2(s–1) respectively.
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